ChemBK
  • Home
  • Product Category

Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine

dimethomorph

CAS: 110488-70-5

Molecular Formula: C21H22ClNO4

  1. Home
  2. Product Category
  3. Organic raw materials
  4. Hydrocarbons
  5. Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine

Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine - Names and Identifiers

Name dimethomorph
Synonyms Festival C
Dimethoroph
dimethomorph
Dimethomorph 0
3-(4-Chlorophenyl)-3-(3,4-diMethoxyphenyl)-1-Morpholinoprop-2-en-1-one
(E,Z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)acryloyl]morpholine
E,Z-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl) acryloyl] morpholine
4-[(2Z)-3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)prop-2-enoyl]morpholine
4-[(2E)-3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)prop-2-enoyl]morpholine
4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl]morpholine
3-(4-Chlorophenyl)-3-(3,4-diMethoxyphenyl)-1-(4-Morpholinyl)-2-propen-1-one
3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-(morpholin-4-yl)prop-2-en-1-one
(E,Z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl]morpholine
Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine
4-(3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl)-morpholin (e,z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl]morpholine (e,z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)acryloyl]morpholine 4-(3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl)morpholine
CAS 110488-70-5
EINECS 404-200-2
InChI InChI=1/C21H22ClNO4/c1-25-19-8-5-16(13-20(19)26-2)18(15-3-6-17(22)7-4-15)14-21(24)23-9-11-27-12-10-23/h3-8,13-14H,9-12H2,1-2H3/b18-14+

Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine - Physico-chemical Properties

Molecular FormulaC21H22ClNO4
Molar Mass387.86
Density1.231g/cm3
Melting Point125-149°C
Boling Point584.9°C at 760 mmHg
Flash Point307.5°C
Water Solubility50 mg l-1 (20-23 °C)
Vapor Presure1 x 10-6 Pa (25 °C)
Appearanceneat
Merck13,3248
BRN8794474
Storage ConditionSealed in dry,Room Temperature
Refractive Index1.58
Physical and Chemical PropertiesMelting point 125-149°C
UseMainly used to control grape downy mildew and potato late blight, usually mixed with Mancozeb

Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine - Risk and Safety

Hazard SymbolsN - Dangerous for the environment
Dangerous for the environment
Risk Codes51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
Safety Description61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
UN IDsUN3077 9/PG 3
WGK Germany2
RTECSQE0478300
ToxicityLD50 in rats (mg/kg): 321 i.p.; 3900 orally; >5000 dermally; LC50 (4-hr inhalation): >4.2 mg/ml (Veenstra, Owen)

Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
fungicide dimethomorph is a broad-spectrum fungicide of morpholine. it has a unique mode of action against fungi of phyctophthora and phytophthora, mainly causing the decomposition of sporangium walls, thus causing the death of the bacteria. Except for zoospore formation and spore swimming period, it has an effect on all stages of the life history of oomycetes, especially in the formation stage of sporangia and oospore. It is more sensitive at extremely low concentrations (
control object and application method 1. control cucumber, balsam pear downy mildew, cruciferous vegetable downy mildew before or at the beginning of the disease, 69% grams of manganese zinc 1500-1995 grams per hectare (69-92 grams of active ingredient), and the spraying amount is 900-1200 liters. Spray once every 7-10 days, and spray 3-4 times continuously. 2. Control pepper blight, grape downy mildew, tobacco black shank, potato late blight before or at the beginning of the onset of spraying, 69% grams of manganese zinc 1995-2505 grams (active ingredient 92-115 grams) per hectare, the spraying amount is 900-1200 liters, and the grape is 2250-3000 liters per metric. Spray once every 7-10 days, and spray 3-4 times continuously.
toxicity dimethomorph is a low-toxicity fungicide according to China's pesticide toxicity classification standard. Acute oral LD50 is greater than 3900 mg/kg in rats, percutaneous LD50 is greater than 2000 mg/kg, and acute inhalation LC50 is greater than 4.24 mg/L in rats. It has no irritation to rabbit skin, slight irritation to eyes, and no sensitization to guinea pigs. Under the test conditions, there was no mutagenic, teratogenic and carcinogenic effects. Rats were fed for 90 days with no effective dose of 200 mg/kg. The drug is moderately toxic to fish, trout acute LC503 mg/L (96 hours), carp LC5014 mg/L (96 hours), Daphnia LC5048 mg/L (48 hours). Under normal use, it is low toxic to bees, and the oral LD50 is greater than 100 μg/head. It has no toxic effect on silkworm. Low toxicity to birds, acute oral LD50 of wild ducks is greater than 2000 mg/kg. Under anaerobic conditions, the half-life in soil is 20 days; under aerobic conditions, the half-life in soil is 50 days. Under ultraviolet light conditions, the E isomer of this compound can be converted into the effective isomer Z. It decomposes quickly in crops and does not accumulate in the environment. The drug has no effect on natural enemies, and the non-effect dose on earthworms is 1000 mg/kg soil. Acute oral LD502400 mg/kg and acute percutaneous LD50 greater than 2000 mg/kg in rats. Slight irritation to eyes, no irritation to skin.
precautions 1. when cucumbers, peppers, cruciferous vegetables and other young hours, the spray amount and dosage are low. Spray to make the liquid cover the blades evenly. 2. Wear protective clothing during application to avoid direct contact with various parts of the body. 3. If the medicine is contaminated with skin, rinse with soap and water. If you take it by mistake, don't vomit and send it to the hospital for treatment as soon as possible. The drug has no antidote and is symptomatic. 4. The drug should be stored in a cool, dry and away from feed and children. 5. Do not use dimethomorph (anke manganese zinc) more than 4 times per season. Pay attention to the use of other fungicides with different mechanisms of action and their rotation application.
synthesis method step 1: xylene and acetic anhydride are stirred and dropwise added with morpholine at normal temperature, slowly raised to 110 ℃ after dropwise addition, refluxed and kept for 5 hours, then dissolved into a distillation kettle and by-product acetic acid. the residual part in the kettle is intermediate acetylmorpholine with a content greater than or equal to 99% and a yield greater than or equal to 90.2%. Step 2: Put xylene, E-benzote and sodium amide into the reaction kettle, stir and add acetylmorpholine dropwise when the temperature is raised to 100 ℃, add dimethomorph dropwise after the drop is raised to 110 ℃ and refluxed for 2 hours, pass it into a water washing kettle to separate waste alkali liquor after the temperature is lowered to 80 ℃, wash to neutral, pass it into a distillation kettle to recover xylene, and centrifuge and dry to obtain dimethomorph with a content of 95% or more and a yield of 76.6% or more. In this method, sodium amide is used to replace sodium tert-butoxide of traditional technology, which greatly improves the reaction speed, shortens the reaction time from 10h to 2h, and greatly improves the production efficiency.
Use Mainly used to control grape downy mildew and potato late blight, usually mixed with mancozeb
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update：2024-04-09 22:01:16
Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine
Supplier List
Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: dimethomorph Request for quotation
CAS: 110488-70-5
Tel: 0086-551-65418684
Email: sales@tnjchem.com
　　　　 info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840 Click to send a QQ message
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Shanghai Yuanye Bio-Technology Co., Ltd.
Multiple Specifications
Product Name: Dimethomorph(mixture of isomer) Visit Supplier Webpage Request for quotation
CAS: 110488-70-5
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409 Click to send a QQ message
Wechat: 18301782025
NanJing Liskon Biological Technology Co.,ltd
Product Name: Dimethomorph Request for quotation
CAS: 110488-70-5
Tel: 025-52110956
Email: lvmu@lskhsw.com
Mobile: 15195951328
QQ: 2468914230 Click to send a QQ messageSend QQ message
Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: dimethomorph Request for quotation
CAS: 110488-70-5
Tel: 0086-551-65418684
Email: sales@tnjchem.com
　　　　 info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840 Click to send a QQ message
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Shanghai Yuanye Bio-Technology Co., Ltd.
Multiple Specifications
Product Name: Dimethomorph(mixture of isomer) Visit Supplier Webpage Request for quotation
CAS: 110488-70-5
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409 Click to send a QQ message
Wechat: 18301782025
NanJing Liskon Biological Technology Co.,ltd
Product Name: Dimethomorph Request for quotation
CAS: 110488-70-5
Tel: 025-52110956
Email: lvmu@lskhsw.com
Mobile: 15195951328
QQ: 2468914230 Click to send a QQ messageSend QQ message
View History
Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine
  • Home
  • Product Category

© 2015, 2023 ChemBK.com All Rights Reserved | Build: 20230617001